CE 5364 Groundwater Transport Phenemona
Fall 2023 Exercise Set 5

LAST NAME, FIRST NAME

R00000000


Purpose :

Apply selected analytical models for reactive transport

Assessment Criteria :

Completion, results plausible, format correct, example calculations shown.



Problem 1 (Problem 11-1, pg. 594)

A contaminated site has been surveyed and a contaminated region $100~ft. \times 150~ft. \times 15~ft.$ was delineated. The average concentration of total petroleum hydrocarbons (TPH) in soil is $10,000~\frac{mg}{Kg}$

Determine:

  1. The total mass of contaminants at the site in kilograms. Assume the soil has a specific gravity, $SG _{soil} \approx 2.0$
  2. Estimate total volume of petroleum hydrocarbons released assuming 50% of the hydrocarbins are lost to volatization, biodegredation, and dissolution (report the answer in gallons). Assume the hydrocarbons were gasoline with a constant specific gravity, $SG_{\text{gasoline}} \approx 0.8$
  3. Estimate the residual saturation of the hydrocarbon-soil system. Assume soil porosity is, $n=0.35$
In [2]:
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Problem 2 (Problem 11-2, pg. 594)

A sampling program at a Supermanfund site indicated the following DNAPL zones:

  • A pool of free phase DNAPL in a stratigraphic depression in an unfractured clay. The pool is 200 $ft^2$ in area and 5 $ft$ thick.
  • A zone of residual DNAPL extending directly underneath an old disposal pit 100 $ft^2$ in area. The residual zone extends through the 5 $ft$ thick unsaturated zone and 15 $ft$ through the saturated zone until it reaches the DNAPL pool.

Supporting data:

Residual saturation in the unsaturated zone: 0.10
Residual saturation in the saturated zone: 0.35
Saturation in the free-phase zone: 0.70
Average porosity in water zone: 0.30

Determine:

  1. The total volume of DNAPL at the site
  2. The recoverable volume using ordinary pumping.
In [1]:
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Problem 3 (Problem 11-4, pg. 595)

Gasoline is found in a monitoring well with $SG=0.80$. A total depth of 6 $ft$ of gasoline is found in the well.

Determine:

  1. Estimated thickness of free-phase LNAPL in the formation.
In [4]:
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